Some alternators rely on residual magnetism to self-excite, or at least initiate excitation. In the case of the six-pole Lucas alternators fitted to motorcycles, these have a solid magnet armature, and do not use excitation at all, and need no current input to initiate output. The infamous emergency start and capacitor ignition for dead or no battery coil ignition situations. Typically excitation is seen in automotive applications, where you have slip rings and winding on the armature, and even there I do not think they apply battery voltage to the armature to get excitation, rather they use residual magnetism to start and then tap off the fields to provide power to the armature windings.
You will have to rectify the AC current output of the alternator into DC, which you do not have to worry about with a dynamo. And like a dynamo, you will need voltage regulation. There are two basic types. The three lead stator (field coils), for six or twelve volts where they successively short out field coil pairs manually (via headlamp switch) to reduce the output. Then the two lead type, twelve volts only, wired internally for full output all the time. Excessive voltage being dumped to ground (and heat) through a zener diode.
The BTH pancake dyno is unregulated, as quite frankly, the output is not high enough to ever ever worry about overcharging the battery! Only a cutout was fitted, to prevent the battery draining down through the dyno when the charging voltage was too low. Which was probably most of the time!
-Doug